In diatonic harmony, tendency tones tend to be one of two things:
- The leading tone, which has a tendency to resolve up to tonic (especially when in an outer voice), and
- Chordal sevenths, which have a tendency to resolve down by step (no matter what voice they're in).
The logic is as follows: if you double a tendency tone, since these tendency tones have a tendency to resolve in a particular way, doubling a tendency tone will result in parallel octaves, which is of course one of the most strident errors in four-part voice leading.